Chromium is the 24th element in the periodic table and its symbol is ‘Cr’. The total number of electrons in chromium is twenty-four. These electrons are arranged according to specific rules of different orbits. The arrangement of electrons in different orbits and orbitals of an atom in a certain order is called electron configuration. The electron configuration of a chromium atom can be done in two ways.
- Electron configuration through orbit (Bohr principle)
- Electron configuration through orbital (Aufbau principle)
Electron configuration through orbitals follows different principles. For example Aufbau principle, Hund’s principle, and Pauli’s exclusion principle. The electron configuration and orbital diagram of chromium is the main topic in this article. Also, valency and valence electrons of chromium and compound formation and bond formation have been discussed. Hopefully, after reading this article you will know in detail about this.
Chromium atom electron configuration through orbit
Scientist Niels Bohr was the first to give an idea of the atom’s orbit. He provided a model of the atom in 1913. The complete idea of the orbit is given there. The electrons of the atom revolve around the nucleus in a certain circular path. These circular paths are called orbit(shell). These orbits are expressed by n. [n = 1,2,3,4 . . . The serial number of the orbit]
K is the name of the first orbit, L is the second, M is the third, and N is the name of the fourth orbit. The electron holding capacity of each orbit is 2n2.
|Shell Number (n)||Shell Name||Electrons Holding Capacity (2n2)|
- n = 1 for K orbit.
The maximum electron holding capacity in K orbit is 2n2 = 2 × 12 = 2.
- For L orbit, n = 2.
The maximum electron holding capacity in L orbit are 2n2 = 2 × 22 = 8.
- n=3 for M orbit.
The maximum electrons holding capacity in M orbit is 2n2 = 2 × 32 = 18.
- n=4 for N orbit.
The maximum electrons holding capacity in N orbit is 2n2 = 2 × 42 = 32.
Therefore, the maximum electron holding capacity in the first shell is two, the second shell is eight and the 3rd shell can have a maximum of eighteen electrons. The atomic number is the number of electrons in that element. The atomic number of chromium is 24. That is, the number of electrons in chromium is twenty-four.
Therefore, the chromium atom will have two electrons in the first shell, and eight in the 2nd shell. According to Bohr’s formula, the third shell will have fourteen electrons but the third shell of chromium will have thirteen electrons and the remaining one electron will be in the fourth orbit. Therefore, the order of the number of electrons in each shell of the chromium(Cr) atom is 2, 8, 13, 1.
Electrons can be arranged correctly through orbits from elements 1 to 18. The electron configuration of an element with an atomic number greater than 18 cannot be properly determined according to the Bohr atomic model. The electron configuration of all the elements can be done through the orbital diagram.
Electron configuration of chromium through orbital
Atomic energy shells are subdivided into sub-energy levels. These sub-energy levels are called also orbital. The most probable region of electron rotation around the nucleus is called the orbital. The sub-energy levels depend on the azimuthal quantum number. It is expressed by ‘l’. The value of ‘l’ is from 0 to (n – 1). The sub-energy levels are known as s, p, d, and f.
|Orbit Number||Value of ‘l’||Number of sub-shells||Number of orbital||Sub-shell name||Electrons holding capacity||Electron configuration|
|3s2 3p6 3d10|
|4s2 4p6 4d10 4f14|
- If n = 1,
(n – 1) = (1–1) = 0
Therefore, the value of ‘l’ is 0. So, the sub-energy level is 1s.
- If n = 2,
(n – 1) = (2–1) = 1.
Therefore, the value of ‘l’ is 0, 1. So, the sub-energy levels are 2s, and 2p.
- If n = 3,
(n – 1) = (3–1) = 2.
Therefore, the value of ‘l’ is 0, 1, 2. So, the sub-energy levels are 3s, 3p, and 3d.
- If n = 4,
(n – 1) = (4–1) = 3
Therefore, the value of ‘l’ is 0, 1, 2, 3. So, the sub-energy levels are 4s, 4p, 4d, and 4f.
- If n = 5,
(n – 1) = (n – 5) = 4.
Therefore, l = 0,1,2,3,4. The number of sub-shells will be 5 but 4s, 4p, 4d, and 4f in these four sub-shells it is possible to arrange the electrons of all the elements of the periodic table.
|Sub-shell name||Name source||Value of ‘l’||Value of ‘m’|
(0 to ± l)
|Number of orbital (2l+1)||Electrons holding capacity|
|p||Principal||1||−1, 0, +1||3||6|
|d||Diffuse||2||−2, −1, 0, +1, +2||5||10|
|f||Fundamental||3||−3, −2, −1, 0, +1, +2, +3||7||14|
The orbital number of the ‘s’ sub-shell is one, three in the ‘p’ sub-shell, five in the ‘d’ sub-shell and seven in the ‘f’ sub-shell. Each orbital can have a maximum of two electrons. The sub-energy level ‘s’ can hold a maximum of two electrons, ‘p’ can hold a maximum of six electrons, ‘d’ can hold a maximum of ten electrons, and ‘f’ can hold a maximum of fourteen electrons.
Aufbau is a German word, which means building up. The main proponents of this principle are scientists Niels Bohr and Pauli. The Aufbau method is to do electron configuration through the sub-energy level. The Aufbau principle is that the electrons present in the atom will first complete the lowest energy orbital and then gradually continue to complete the higher energy orbital.
The energy of an orbital is calculated from the value of the principal quantum number ‘n’ and the azimuthal quantum number ‘l’. The orbital for which the value of (n + l) is lower is the low energy orbital and the electron will enter that orbital first.
|Orbital||Orbit (n)||Azimuthal quantum number (l)||Orbital energy (n + l)|
Here, the energy of 4s orbital is less than that of 3d. So, the electron will enter the 4s orbital first and the electron will enter the 3d orbital when the 4s orbital is full. The method of entering electrons into orbitals through the Aufbau principle is 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d.
The first two electrons of chromium enter the 1s orbital. The s-orbital can have a maximum of two electrons. Therefore, the next two electrons enter the 2s orbital. The p-orbital can have a maximum of six electrons. So, the next six electrons enter the 2p orbital. The second orbit is now full. So, the remaining electrons will enter the third orbit.
Then two electrons will enter the 3s orbital and the next six electrons will be in the 3p orbital of the third orbit. The 3p orbital is now full. So, the next two electrons will enter the 4s orbital and the remaining four electrons will enter the 3d orbital.
But the orbital wants to be half-filled or full-filled by electrons. Because the atom may be in a more stable state when the orbital is half-filled and full-filled. Therefore, an electron of 4s orbital completes a half-filled 3d orbital by jumping into a 3d orbital. So, the chromium full electron configuration will be 1s2 2s2 2p6 3s2 3p6 3d5 4s1.
Note: The short electron configuration of chromium is [Ar] 3d5 4s1. When writing an electron configuration, you have to write serially.
How to write the orbital diagram for chromium?
To create an orbital diagram of an atom, you first need to know Hund’s principle and Pauli’s exclusion principle. Hund’s principle is that electrons in different orbitals with the same energy would be positioned in such a way that they could be in the unpaired state of maximum number and the spin of the unpaired electrons will be one-way.
And Pauli’s exclusion principle is that the value of four quantum numbers of two electrons in an atom cannot be the same. To write the orbital diagram of chromium(Cr), you have to do the electron configuration of chromium. Which has been discussed in detail above. 1s is the closest and lowest energy orbital to the nucleus. Therefore, the electron will first enter the 1s orbital.
According to Hund’s principle, the first electron will enter in the clockwise direction and the next electron will enter the 1s orbital in the anti-clockwise direction. The 1s orbital is now filled with two electrons. Then the next two electrons will enter the 2s orbital just like the 1s orbital.
The next three electrons will enter the 2p orbital in the clockwise direction and the next three electrons will enter the 2p orbital in the anti-clockwise direction. Then next two electrons will enter the 3s orbital just like the 1s orbital and then the next six electrons will enter the 3p orbital just like the 2p orbital.
The 3p orbital is now full. So, next an electron will enter the 4s orbital in the clockwise direction and the remaining five electrons will enter the 3d orbital in the clockwise direction. This is clearly shown in the figure of the orbital diagram of chromium.
Chromium ion(Cr2+, Cr3+) electron configuration
The ground state electron configuration of chromium is 1s2 2s2 2p6 3s2 3p6 3d5 4s1. This electron configuration shows that the last shell of chromium has an electron and the d-orbital has a total of five electrons. Therefore, the valence electrons of chromium are six.
There are two types of chromium ions. The chromium atom exhibits Cr2+ and Cr3+ ions. The chromium atom donates an electron in 4s orbital and an electron in 3d orbital to convert chromium ion(Cr2+).
Cr – 2e– → Cr2+
Here, the electron configuration of chromium ion(Cr2+) is 1s2 2s2 2p6 3s2 3p6 3d4. The chromium atom donates an electron in 4s orbital and two electrons in 3d orbital to convert to chromium ion(Cr3+).
Cr – 3e– → Cr3+
The electron configuration of chromium ion(Cr3+) is 1s2 2s2 2p6 3s2 3p6 3d3. Chromium exhibits +2, +3 and +6 oxidation states. The oxidation state of the element changes depending on the bond formation.
Compound formation of chromium
Chromium participates in the formation of bonds through its valence electrons. We know that the valence electrons in chromium are six. This valence electron participates in the formation of bonds with atoms of other elements. The electron configuration of chlorine shows that the valence electrons of chlorine are seven.
The chromium atom donates its valence electrons to the chlorine atom and the chlorine atom receives those electrons. As a result, chlorine acquires the electron configuration of argon. Chromium(III) chloride(CrCl3) is formed by the exchange of electrons between one atom of chromium and three atoms of chlorine. Chromium(III) chloride(CrCl3) is ionic bonding.
What is the symbol for chromium?
Ans: The symbol for chromium is ‘Cr’.
How many electrons does chromium have?
Ans: 24 electrons.
How do you write the electron configuration for chromium?
Ans: Chromium electron configuration is 1s2 2s2 2p6 3s2 3p6 3d5 4s1.
How many valence electrons does chromium have?
Ans: Six valence electrons.
What is the valency of chromium?
Ans: The valency of chromium is 2.